An investigation on the role of Hydrogen in metals

Abstract

Recently, grave explosions in the oil and gas transport tubes, as well
as, the rapid failure of the machine parts in service, were caused by hydrogen
cracking. During solidification of metals, in casting ,welding, cathodic
charging, etc., the hydrogen can enter in metals and cause premature cracking.
The hydrogen embrittlement in metals is accompanied with a charge in the type
of fracture surface ( Intergranular or Interaganular ) and a decrease or in
certain casesan increase in the ductility of metals. The embrittlement by
hydrogen depends on two factors: (1) When the amount of hydrogen is in the
order of 1-2 ppm , the decohesion, between atoms in the crystal lattice is
the predominent factor, (11) When the hydrogen concentration in the metal is
more than 1-2 ppm, the very high pressure of H molecules in microcracks
plays an essential role to cause brittle fracture. But, hydrogen cannot pin
the dislocations, as it was not able to increase the elastic limit in many
studied cases.
In this article, it has been tried to compare the results and suggestions
obtained by the author with the more recent works in this field.
Consequently, attempts have been made to clear some of the questions in this
subject by deducing the common points and contradictions in these works.